3. Two-part marine epoxy resin
There are many different brands of epoxy resin available but only true two-part marine epoxies should be used for plywood aquarium builds. These epoxies have a long established and successful history in waterproofing wooden boats. They differ from epoxy paints in that they are 100% solids. Several brands are available but some tried and true options include:
West Systems 105 (one of the more expensive):
http://www.westsystem.com/ss/epoxy-resins-and-hardeners
US Composites (cheaper option):
http://www.shopmaninc.com/epoxy.html
Max ACR (newer, relatively affordable epoxy being marketed specifically for aquariums):
http://cgi.ebay.com/EPOXY-RESIN-AQU...459?pt=LH_DefaultDomain_0&hash=item4831f75a83 (search for the seller “polymerproducts” on ebay)
There are many other marine epoxy brands out there that you could use but these three cover the spectrum of price and have all been successfully used in waterproofing plywood aquariums. Marine epoxies come as a resin and a separate hardener that have to be mixed in a precise ratio. It is best to use slow hardeners when sealing a tank with these products to give you a longer working time and better penetration into the wood. The West Systems use guide is an excellent resource to learn how to properly use marine epoxy:
http://westsystem.com/ss/use-guides/
I strongly recommend reading every section of the guide before beginning to work with these products.
Marine epoxies can be used as a standalone product to provide a completely waterproof and non-toxic coating for a plywood tank. However, they are fairly brittle when cured and can be susceptible to stress fractures at seams and damage from impact which will compromise the barrier coating. Please see
http://www.jonolavsakvarium.com/eng_diy/epoxy_test/article.html
The best way to avoid these issues is to incorporate a layer of fiberglass cloth into the epoxy resin. Epoxy resins can be used to wet out fiberglass cloth in much the same way as polyester fiberglass resin but offer several advantages. There is not strong smell, the cured resin layer is completely waterproof and non toxic and is slightly less brittle than polyester resin. With the exception of cost, epoxy resin is an all around better option than polyester fiberglass resin. As discussed above, wetting out fiberglass cloth does take a little practice but with a little skill is an excellent way to add significant structural strength to your aquarium.
When used with thickening agents such as colloidal silica, marine epoxy can also function as an excellent adhesive, particularly for slightly loose joints or joints where you cannot deliver high clamping pressure. It can therefore also be useful as a waterproof adhesive during the construction and assembly of a plywood aquarium.
Silicone will adhere well to epoxy resin so waterproof your tank first and then silicone in your glass viewing windows. Epoxy resins can be tinted if you want a colored coating but will usually still show some wood grain. Sweetwater epoxy can be used as a topcoat if solid color is desired.
Two part marine epoxy summary
Pros: Can add significant structural strength to a build, particularly when used with fiberglass. Minimal smell. Effective standalone waterproof barrier layer. Silicone will stick to it making window installation easy.
Cons: Expensive, can suffer from stress fractures if used without fiberglass on an inadequately supported structure.