Your tank looks great, and there may be room for a Crenicichla zebrina.
If you do add it, you may want to also consider adding a wave maker to produce a linear current, zebrina comes from areas where current is strong.
And if you do add it, depending on its size want to double your water change schedule as it hits adulthood, they can easily hit 12" and can be a serious nitrate producer, and they can be sensitive to elevated nitrate.
Here is an example of the type waters they come from.
View attachment 1540548
Or..... since you are little paranoid about the viability of the newly acquired 200+ gal, use the 200 as a heavily planted regugium/terrerium to help reduce nitrate.
As a sump, you might need only fill it to half, or 2/3 its stated volume.