msjinkzd,
A few things.
You don't want to drill into the acrylic. Any flex and you have disaster. Installing pins behind the acrylic through the angle to secure it would be a better idea.
3/4" would be fine if you're using 2" angle to frame it. Your window would be 32" viewable correct? Length doesn't matter that much.
Laird plastics is a great place to get your cell cast acrylic from. My 2" piece was only a couple hundred more than the 1.5" and a few hundred more than the 1.25" piece of the same size. 1" is probably about $100 more than 3/4" and definitely worth the price.
Check with Nationwide Plastics
http://www.nationwideplastics.net/ and ACI Plastics
http://www.aciplastics.com/ for price quotes first before you call Laird.
Be sure to verify the dimensions of the piece you order. I thought ordering a 48x96 piece meant I'd get a 48x96 piece and ended up with a 50x99 piece.
Framed windows can utilitize thinner acrylic/glass than windows that span unsupported distances.
The max I'd go with 1/2" would be 30", but that's still pushing it.