Topping off freshwater aquarium with tap water?

  • We are currently upgrading MFK. thanks! -neo
Chlorine can react with organics. Chloramine probably won't, at least not very quickly. Even if it did, the reaction between chlorine and organics leads to the formation of organic chloramines which are just as toxic as chloramine while being more resistant to dechlorination. They also can't be detected using conventional tests.

0.4 mg/L chloramine is plenty dangerous.

The question is topping off a tank and not doing 100% w/c without adding a dechlorinator, we all know 4ppm of chloramine is dangerous. Diluted, by a factor of ten probably wont harm anything. Chloramine will eventually act with organics and carbon in a filter will eventually make it safe as well. But if you dont have any carbon its usually fine anyways, water supplies heavily saturate their water with calcium carbonate to make sure it doesn't wreck havoc on their distribution system. Being so saturated comes with a high ph (7-8ph) which organic chloramines are generally listed as inactive in disinfection.
 
  • Like
Reactions: Finthusiast
The question is topping off a tank and not doing 100% w/c without adding a dechlorinator, we all know 4ppm of chloramine is dangerous. Diluted, by a factor of ten probably wont harm anything. Chloramine will eventually act with organics and carbon in a filter will eventually make it safe as well. But if you dont have any carbon its usually fine anyways, water supplies heavily saturate their water with calcium carbonate to make sure it doesn't wreck havoc on their distribution system. Being so saturated comes with a high ph (7-8ph) which organic chloramines are generally listed as inactive in disinfection.

4 ppm chloramine dliuted ten-fold is 0.4 mg/L which is still quite toxic.

Chloramine won't react with organics and if it does it doesn't become any less toxic.
 
  • Like
Reactions: Finthusiast
Wow thanks you everyone for all this info. I appreciate the advice and I do have city tap water. I did not realize that about the “soup” effect I will do the water change as stated by duanes as it seems to be the safest thing to do for my fish. I have done the top off already but glad to have been given all this info before I made it a habit. Thanks again to all your posts!
 
  • Like
Reactions: Jexnell and Niki_up
4 ppm chloramine dliuted ten-fold is 0.4 mg/L which is still quite toxic.

Chloramine won't react with organics and if it does it doesn't become any less toxic.

Well I was thinking about the threshold or breakpoint in chlorination to where the residual would be negatively impactful to the fish.

The volume op has is topping off 5 gallons of water into 70 gallons making the total volume 75 gallons. I just threw a easy dilution factor of 10 because i can do it without any thinking but lets use OP's gallon.

5 gallons of 75 gallons is 6.67%
5 gallons having 4ppm
70 gallons having 0ppm
changing to liters will make it easier as a ppm is just a way to say mg/liters

topping off
5 gallons = 18.92705 liters still 6.6% of the tanks volume
initial volume having 0mg/l of chloramines
70 gallons = 264.979 liters
total volume
75 gallons = 283.906 liters

dilution formula is c1v1=c2v2

were left with
4mg/l * 18.92705 = c2 * 283.906
when solved is
.266 mg/l = c2 (final concentration)

So we know the tanks ppm or mg/l will be .266ppm for that 283.906 liters or for that 75 gallon tank. I couldnt find any scientific studies on chloramine levels and fish to show what levels are toxic that were credible but im going out on a limb and saying .266ppm of chloramines isnt that harmful. Were talking about .266 parts of chlorine per million gallons of water lol... The epa sets the maximum to be .4ppm of total chlorine which is a mixture of free chlorine and also combined chlorines, most municipal water supplies dont use straight chloramines. By the time it goes throughout the distribution center and reaches your house going through 100 year old pipes in the streets its not .4ppm as that is a significant chlorine demand. Only time the water supply uses .4ppm of straight chloramines is if its snow melt or head waters (first use), they will use uv to disinfect and then have .4ppm of chloramines leaving the water treatment plant. But again by the time it gets to your house its probably closer to 2-3ppm which drastically lowers the .266ppm in OP's tank. And even further lowers if hes in a place where they use free chlorine and combined chlorine.


Ive topped off like this this many times in the past years ago and those same fish are still with me +5 years nearing 10 years. Sure people probably lost sensitive fish to topping off a tank without any dechlorinator but its really isnt that dangerous. As i mentioned any activated carbon you have in your filters will render the chloramines inactive. Of course just dose the water your adding or whole tank and then add water is always recommended. But its not as dangerous as your leading on, they do act with organics, just not as readily as free chlorine does usually with nitrogen creating the organic chloramines. The debate isnt whether it reacts with organics (which it does creating organic chloramines) its if the small amount of chloramines that were diluted will harm fish. At that level most fish are fine and wont skip a beat.
 
  • Like
Reactions: Finthusiast
Thanks for taking the time to post this info. I will check back here if I got any more questions or even just an update soon on a new thread. :D
 
Just a for instance....
lets say your tank is down 2 gallons from evaporation, so as opposed to simply topping off, you remove 3 more gallons of old water from the tank, .....so you only need to replace 5.
If it were me, on such a small water change, I'd just use a bucket or some jugs for a water change, put the required few drops of dechlor in each jug or bucket, and then add the water.
In this case, there is no need to over treat the entire tank, just the exact amount water going in.
Dechlorination with todays products is basically instantaneous.
I only dechlorinate for the entire tank size when doing larger water changes, say a 50% or more and then tend to err on the side of adding a 50% dose of declorinator for on large tanks.
One caveat.... I have tested this application myself, to see how my Dechlorinator works at a 50% volume.
Don't you kids try this a home, unless you test for your own situation first.
When I livedin the U.S. my tap water would leave the tap at 1.26ppm.

After adding Sodium Thiosulfate to 50% of the tanks volume, (on a 50% water change) my tank water would immediately present 00.1ppm
 
Just an additional thought here. Are you running lids? If you have well fitting lids you shouldn't need top off. The tank will need a water change way before evaporation will affect water level. Also I only dechlorinate for the amount of new water going in.
 
  • Like
Reactions: Finthusiast
I use glass lids for my 75g I honestly am not sure how my water level got to be so much lower this time maybe I started kinda low on my last water change without realizing till halfway through the week. Things are going well right now and will be posting an update soon. Thanks again for info.
 
There are some simple steps to be able to use tap water in the aquarium that you should know. To deal with harmful substances in tap water, you must first check some factors, such as pH, calcium carbonate, heavy metals, etc., in tap water and remove them. After removing chlorine and other unwanted metals from tap water, there is a good chance that there are still other harmful substances found in the water. Applying a balm is a necessity to get rid of this unwanted toxic substance.
 
The only thing lost to evaporation is water, so don't add anything other than water; no added salts or other mumbo-jumbo that the tank "requires". Certainly, dechlorinate the top-up water.

Honestly, I can't recall the last time I have ever "topped-up" a tank. My tanks all have lids, and if evaporation has dropped my water level far enough to be noticeable, then it's already past-due for a water change.
 
MonsterFishKeepers.com