NUMA has a beautiful 2500 gallon concrete tank. He could probably answer a lot of your questions. I love the cement "roots" he has in his tank.
http://www.monsterfishkeepers.com/forums/threads/my-2500-gallon-concrete-mega-tank-project.438417/
I believe SeaQuatic seals their concrete tanks with polyurea
http://seaquaticaquariums.com/aquariums/concrete-aquariums/
Instead of real trees, have trees made from Zoopoxy
http://www.polygem.com/general-gallery
http://www.monsterfishkeepers.com/forums/threads/my-2500-gallon-concrete-mega-tank-project.438417/
I believe SeaQuatic seals their concrete tanks with polyurea
http://seaquaticaquariums.com/aquariums/concrete-aquariums/
Instead of real trees, have trees made from Zoopoxy
http://www.polygem.com/general-gallery