Wow, this thing just does not want to hold water. I am starting to wonder if the previous owner chased this leak around for a few months or years before throwing in the towel and selling it.
It's more than twice the size of anything I've ever built...it's about 8x the size of the biggest glass tank I've ever built...so I'm afraid to make any suggestions. But it's not my house, so...I will!
I wonder: is there a chance that during the original construction of this tank, the bottom glass (which, as others have commented, is pretty dang thin...) might have been laying on a surface which was not completely flat? A very slight twist, cause by warped wood surfaces and/or perhaps some small obstruction lahying un-noticed under the glass, might perhaps have allowed the big-yet-thin sheet of glass to flex almost imperceptibly. Then, the four sides were assembled on top of it, the silicone cured, and the tank then moved into position. The stand, being perfectly flat and level, would not be supporting the bottom completely or evenly. I'm not talking about giant gaps here, perhaps enough to slip a coupe sheets of paper between the bottom and the stand in one corner or two.
You then fill it with water, the weight of which is pressing down on the entire bottom, which flexes slightly as the higher corners press down to the stand. This then stresses the structural bead between the sides and the bottom; it was okay for a few years but as the silicone ages the constant flexing begins to tear it, resulting in your leak.
How about the four vertical corner seams? Is each of them perfectly smooth, or does one of the sides sit slightly proud of the adjoining side at any point? That might be an indicator of a tank that isn't built completely square and true, but is trying to be under the weight of water.
Just thinking out loud here; I've got nothing better.
It's more than twice the size of anything I've ever built...it's about 8x the size of the biggest glass tank I've ever built...so I'm afraid to make any suggestions. But it's not my house, so...I will!
I wonder: is there a chance that during the original construction of this tank, the bottom glass (which, as others have commented, is pretty dang thin...) might have been laying on a surface which was not completely flat? A very slight twist, cause by warped wood surfaces and/or perhaps some small obstruction lahying un-noticed under the glass, might perhaps have allowed the big-yet-thin sheet of glass to flex almost imperceptibly. Then, the four sides were assembled on top of it, the silicone cured, and the tank then moved into position. The stand, being perfectly flat and level, would not be supporting the bottom completely or evenly. I'm not talking about giant gaps here, perhaps enough to slip a coupe sheets of paper between the bottom and the stand in one corner or two.
You then fill it with water, the weight of which is pressing down on the entire bottom, which flexes slightly as the higher corners press down to the stand. This then stresses the structural bead between the sides and the bottom; it was okay for a few years but as the silicone ages the constant flexing begins to tear it, resulting in your leak.
How about the four vertical corner seams? Is each of them perfectly smooth, or does one of the sides sit slightly proud of the adjoining side at any point? That might be an indicator of a tank that isn't built completely square and true, but is trying to be under the weight of water.
Just thinking out loud here; I've got nothing better.