i tried scrubbing it with 2 gallons of white wine vinegar had little effect. Been onto the tech people at K.A. they said if I wanted they would send someone out to do tests for me. After talking to them it sounds like I need to just wait a bit and drop the ph slowly. Doing this quickly using chemicals has the risk once the ph has dropped it might swing back.
As a back up plan I can fibre glass the pond. Not sure a pond paint will stick to tanking as it contains silicon (not sure how). I know its difficult to render or skim over because little sticks to it. Spring time if the ph has not settled I will go for plan B.